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一种具有超高温工程应用潜力的氮化物增强NbMoTaWHfN难熔高熵合金 Article
万义兴, 程延海, Yongxiong Chen, Zhibin Zhang, Yanan Liu, Haijun Gong, Baolong Shen, Xiubing Liang
《工程(英文)》 2023年 第30卷 第11期 页码 110-120 doi: 10.1016/j.eng.2023.06.008
Refractory high-entropy alloys (RHEAs) have promising applications as the new generation of high-temperature alloys in hypersonic vehicles, aero-engines, gas turbines, and nuclear power plants. This study focuses on the microstructures and mechanical properties of the NbMoTaW(HfN)x (x = 0, 0.3, 0.7, and 1.0) RHEAs. The alloys consist of multiple phases of body-centered cubic (BCC), hafnium nitride (HfN), or multicomponent nitride (MN) phases. As the x contents increase, the grain size becomes smaller, and the strength gradually increases. The compressive yield strengths of the NbMoTaWHfN RHEA at ambient temperature, 1000, 1400, and 1800 °C were found to be 1682, 1192, 792, and 288 MPa, respectively. The high-temperature strength of this alloy is an inspiring result that exceeds the high temperature and strength of most known alloys, including high-entropy alloys, refractory metals, and superalloys. The HfN phase has a significant effect on strengthening due to its high structural stability and sluggish grain coarsening, even at ultra-high temperatures. Its superior properties endow the NbMoTaWHfN RHEA with potential for a wide range of engineering applications at ultra-high temperatures. This work offers a strategy for the design of high-temperature alloys and proposes an ultra-high-temperature alloy with potential for future engineering applications.
关键词: Refractory high-entropy alloy High temperature Mechanical property Microstructure Strengthening mechanism
《机械工程前沿(英文)》 2023年 第18卷 第1期 doi: 10.1007/s11465-022-0727-x
关键词: laser powder bed fusion (L-PBF) in situ alloying high-entropy alloys heat treatment rapid synthesis
李天昕,王书道,卢一平,曹志强 ,王同敏,李廷举
《中国工程科学》 2023年 第25卷 第3期 页码 170-181 doi: 10.15302/J-SSCAE-2023.03.016
随着世界科技水平的快速发展以及国民经济建设对高性能合金材料的迫切需求,传统单一主元合金逐渐不能满足人们与日俱增的使役需求。高熵合金因其独特的物理、化学以及力学性能,极大地拓展了金属材料成分设计范围,有望在国防、航空、航天、海洋、核能、医疗、新能源等重大工程领域发挥重要作用。本文结合各领域对先进高熵合金材料的具体需求,梳理了高熵合金材料的特征和内涵,分析了高熵合金材料发展的整体形势与前景,厘清了国内外高熵合金的发展现状。在此基础上,指出了我国高熵合金领域存在的差距和不足,我国高熵合金部分基础原材料依赖进口,严重威胁产业链安全;高熵合金产学研用体系尚未健全,工业化应用方面的研发投入有待提高。针对上述问题,研究建议,加强高熵合金材料研发的顶层设计,完善产业政策;加强企业和科研机构的对接和沟通;完善高熵合金材料标准、测试、表征、评价体系;推进人才队伍建设;降低材料成本,打造高附加值产品,促进我国先进高熵合金材料产业朝着体系化、绿色化、高端化、智能化方向发展。
《能源前沿(英文)》 doi: 10.1007/s11708-023-0892-6
关键词: high-entropy electrocatalysis synthetic methods water-electrolysis hydrogen and oxygen evolutions
High-order phase-field model with the local and second-order max-entropy approximants
Fatemeh AMIRI
《结构与土木工程前沿(英文)》 2019年 第13卷 第2期 页码 406-416 doi: 10.1007/s11709-018-0475-5
关键词: second-order maximum entropy local maximum entropy second- and fourth-order phase-field models B-spline
Grindability of high-temperature alloy with ceramic alumina wheels
ZHANG Hongxia, CHEN Wuyi, CHEN Zhitong
《机械工程前沿(英文)》 2008年 第3卷 第2期 页码 139-145 doi: 10.1007/s11465-008-0040-3
关键词: metallographic topography grinding GH2132 resistance decrease
《能源前沿(英文)》 页码 751-762 doi: 10.1007/s11708-023-0895-3
关键词: FA dehydrogenation face-centred cubic structures PdAu solid solution alloy nanoparticles slow synthesis methodology SMSI effect
《医学前沿(英文)》 2022年 第16卷 第2期 页码 285-294 doi: 10.1007/s11684-021-0843-8
关键词: CAR-T cell therapy refractory diffuse large B-cell lymphoma cytokine release syndrome dose-limiting toxicity
Principle of maximum entropy for reliability analysis in the design of machine components
Yimin ZHANG
《机械工程前沿(英文)》 2019年 第14卷 第1期 页码 21-32 doi: 10.1007/s11465-018-0512-z
关键词: machine components reliability arbitrary distribution parameter principle of maximum entropy
Manli LUO, Jing LIU
《能源前沿(英文)》 2013年 第7卷 第4期 页码 479-486 doi: 10.1007/s11708-013-0277-3
关键词: heat exchanger liquid metal mini-channel heat dissipation heat transfer coefficient
姜业欣, 娄花芬, 解浩峰, 李廷举, 宋克兴, 刘雪峰, 运新兵, 汪航, 肖柱, 李周
《中国工程科学》 2020年 第22卷 第5期 页码 84-92 doi: 10.15302/J-SSCAE-2020.05.015
本文针对我国电工电子、新一代移动通信、新能源汽车、航空航天、轨道交通等新兴产业和重大工程领域对先进铜合金材料的典型需求,梳理了国内外高强高导铜合金、耐磨耐蚀铜合金、超高强弹性铜合金、先进铜基复合材料、高精度铜及铜合金细微丝、超薄箔材的发展现状和差距。在此基础上分析了上述先进铜合金的典型市场需求,论证了我国先进铜合金材料的中长期发展目标和关键技术。研究还提出了促进“产学研用管”的统筹规划和一体化发展,提升装备开发、技术研发和市场拓展能力,强化产品标准研究与制定,建立青年科技骨干人才培养体系的产业发展建议。期望以国民经济重点领域和国防建设需求为导向,通过铜合金材料、装备、技术、产业化等自主创新体系的完善,促进我国先进铜合金材料绿色、高端、智能发展。
Maximum entropy based finite element analysis of porous media
Emad NOROUZI, Hesam MOSLEMZADEH, Soheil MOHAMMADI
《结构与土木工程前沿(英文)》 2019年 第13卷 第2期 页码 364-379 doi: 10.1007/s11709-018-0470-x
关键词: maximum entropy FEM fully coupled multi-phase system porous media
代从新,姚勇,王任直
《中国工程科学》 2012年 第14卷 第8期 页码 96-99
硼中子俘获疗法在脑胶质瘤治疗研究中已经取得很大进展,但由于脑胶质瘤的特性以及缺乏与肿瘤高亲和力的掺硼药物,硼中子俘获治疗的效果并不十分理想。此外,难治性垂体腺瘤具有很多与脑胶质瘤相同的特点,硼中子俘获疗法可能具有一定的意义。文章重点介绍硼中子俘获疗法治疗脑胶质瘤的研究现状和治疗难治性垂体腺瘤的可能性。
Shenghua Ye, Gaoren Li
《化学科学与工程前沿(英文)》 2018年 第12卷 第3期 页码 473-480 doi: 10.1007/s11705-018-1724-9
The polypyrrole(PPy)@NiCo hybrid nanotube arrays have been successfully fabricated as a high performance electrocatalyst for hydrogen evolution reaction (HER) in alkaline solution. The strong electronic interactions between PPy and NiCo alloy are confirmed by X-ray photoelectron spectroscopy and Raman spectra. Because these interations can remarkably reduce the apparent activation energy (Ea) for HER and enhance the turnover frequency of catalysts, the electrocatalytic performance of PPy@NiCo hybrid nanotube arrays are significantly improved. The electrochemical tests show that the PPy@NiCo hybrid catalysts exhibit a low overpotential of ~186 mV at 10.0 mA·cm−2 and a small tafel slope of 88.6 mV·deg−1 for HER in the alkaline solution. The PPy@NiCo hybrid nanotubes also exhibit high catalytic activity and high stability for HER.
关键词: NiCo alloy polypyrrole hybrid nanotube electrocatalyst hydrogen evolution reaction
Degradation of refractory organics in concentrated leachate by the Fenton process: Central composite
Senem Yazici Guvenc, Gamze Varank
《环境科学与工程前沿(英文)》 2021年 第15卷 第1期 doi: 10.1007/s11783-020-1294-1
关键词: Concentrated leachate Fenton oxidation Central composite design Biodegradability Inert COD
标题 作者 时间 类型 操作
一种具有超高温工程应用潜力的氮化物增强NbMoTaWHfN难熔高熵合金
万义兴, 程延海, Yongxiong Chen, Zhibin Zhang, Yanan Liu, Haijun Gong, Baolong Shen, Xiubing Liang
期刊论文
Rapid alloying of CoCrFeMnNi high-entropy alloy from elemental feedstock toward high-throughput synthesis
期刊论文
High-entropy catalysts for electrochemical water-electrolysis of hydrogen evolution and oxygen evolution
期刊论文
High-order phase-field model with the local and second-order max-entropy approximants
Fatemeh AMIRI
期刊论文
Grindability of high-temperature alloy with ceramic alumina wheels
ZHANG Hongxia, CHEN Wuyi, CHEN Zhitong
期刊论文
Formic acid dehydrogenation reaction on high-performance PdAu alloy nanoparticles prepared by the eco-friendly
期刊论文
Phase I study of CBM.CD19 chimeric antigen receptor T cell in the treatment of refractory diffuse large
期刊论文
Principle of maximum entropy for reliability analysis in the design of machine components
Yimin ZHANG
期刊论文
Experimental investigation of liquid metal alloy based mini-channel heat exchanger for high power electronic
Manli LUO, Jing LIU
期刊论文
Maximum entropy based finite element analysis of porous media
Emad NOROUZI, Hesam MOSLEMZADEH, Soheil MOHAMMADI
期刊论文
Polypyrrole@NiCo hybrid nanotube arrays as high performance electrocatalyst for hydrogen evolution reaction
Shenghua Ye, Gaoren Li
期刊论文